| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터) |
| 권호 |
34권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Reversible addition-fragmentation chain transfer (RAFT) polymerization of adamantane substituted poly(methyl methacrylate)s |
| 초록 |
Living radical polymerizations of 3-hydroxy-1-adamantyl methacrylate (HAdMA) and 2-ethyl-2-adamantyl methacrylate (EAdMA) were performed via the reversible addition-fragmentation chain transfer (RAFT) method using 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN) as a chain transfer agent. HAdMA exhibited controlled polymerization characteristics, that is, first order kinetics of polymerization, linear evolution of molecular weight with increasing monomer conversion, and narrow polydispersity index. When the same polymerization conditions were applied to EAdMA, methacrylic acid originated from the decomposition of EAdMA was observed. The details for the characterization of polymers will be given in the meeting. |
| 저자 |
이원기1, 차상호1, 손해성1, 이종찬1, 김명선2, 윤효진2, 백세경2, 김수경2, 함지윤2, 김영호2, 채승기2, 이준경3, 이재우3, 김재현3
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| 소속 |
1서울대, 2(주)삼성전자, 3(주)동진쎄미켐 |
| 키워드 |
RAFT; living radical polymerization; adamantane; methacrylate
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| E-Mail |
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