| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Kinetic Study of the Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization of Adamantyl-Substituted Methyl Methacrylate Derivatives |
| 초록 |
Controlled/Living radical polymerizations of 3-hydroxy-1-adamantyl methacrylate (HAdMA) and 2-ethyl-2-adamantyl methacrylate (EAdMA) were performed using the reversible addition-fragmentation chain transfer (RAFT) method in the presence of 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN) as a chain transfer agent. The polymerization of HAdMA exhibited controlled/living polymerization characteristics such as pseudo first-order kinetics of polymerization, linear evolution of molecular weight with increasing monomer conversion, and narrow polydispersity index. In the same polymerization conditions, the decomposition of EAdMA to methacrylic acid was observed. A detailed characterization of the polymerizations will be given in the meeting. |
| 저자 |
김동균1, 차상호1, 손해성1, 이원기1, 이종찬1, 김명선2, 윤효진2, 백세경2, 김수경2, 함지윤2, 김영호2, 채승기2, 이준경3, 이재우3, 김재현3
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| 소속 |
1서울대, 2(주)삼성전자, 3(주)동진쎄미켐 |
| 키워드 |
RAFT; controlled/living radical polymerization; adamantane; methyl methacrylate
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| E-Mail |
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