초록 |
Various conjugated polymers have been widely introduced to thermoelectric (TE) nanocomposite system blending polymers with carbon nanotubes (CNTs) to achieve the optimized TE characteristics, such as electrical conductivity, seebeck coefficient, and thermal conductivity. Herein, we designed novel approach to control TE properties of nanocomposites mixing conjugated polymers with different molecular ordering with carbon nanotubes for developing high performance TE nanocomposites. The different molecular ordering of conjugated polymers had a great influence on the microstructural properties of TE nanocomposite films. Especially, conjugated polymer with face-on orientation was significantly effective to improve thermoelectric properties and power generation of TE nanocomposite film, inducing neat alignment in a horizontal direction of CNTs in nanocomposite film. |