화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 고분자구조 및 물성
제목 High-density HEX Cylindrical Microdomains Using Blends of Block Copolymers
초록 This study presents a binary blend of block copolymers that fabricates inverted cylindrical microdomains. This blend system consists of polystyrene-block-poly(2-vinylpyridine) (PS-b-P2VP) and polystyrene-block-poly(hydroxylstyrene) (PS-b-PHS). Hydrogen bond interactions occur between P2VP and PHS and affect the interface curvature and the phase behavior of binary blends. The blends formed hexagonally-packed cylindrical microdomains and the volume fraction of the cylinder parts was > 0.6. The morphology of blends was unexpected in comparison with usual block copolymer systems and achieved high-density HEX cylindrical patterns.
저자 강석원, 김진곤
소속 POSTECH
키워드 Block copolymers; nanostructures; self-assembly
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