| 학회 | 한국고분자학회 |
| 학술대회 | 2002년 가을 (10/11 ~ 10/12, 군산대학교) |
| 권호 | 27권 2호, p.256 |
| 발표분야 | 고분자 합성 |
| 제목 | Cu(I)-mediated Radical Polymerization of N-Isopropylacrylamide |
| 초록 | Transition metal-mediated radical polymerization has been well-known as a powerful tool to prepare polymers with controlling the molecular weight and the architecture via radical mechanism. Copper halide/tertiary amine complexes have been used in radical polymerizations of methyl methacrylate or styrene in non-aqueous medium such as toulene at high temperature relatively. Polymerization of N-isopropylacrylamide has been known for a long time to produce the corresponding thermo-responsive hydrogel exhibiting an abrupt phase transition near 32oC. In this respect, we found new methodology to prepare the hydrogel via transition metal-mediated radical polymerization in aqueous medium. Especially, a proper choice of alkyl halide as an initiator was found to play an important role in the polymerization of water-soluble monomer. We will discuss the reaction condition to control the molecular weight of the formed hydrogel in this presentation. |
| 저자 | 김상섭1, 이종찬2, 진용현*3, 류한욱*4, 박경원*, 김광웅*, 김정안* |
| 소속 | 1서울대, 2응용화학부, 3*한국과학기술(연), 4고분자하이브리드센터 |
| 키워드 | Transition metal-mediated polymerization; N-isopropylacrylamide; hydrogel |
