| 학회 |
한국공업화학회 |
| 학술대회 |
2019년 가을 (10/30 ~ 11/01, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 |
23권 2호 |
| 발표분야 |
우수논문(구두)_박사과정 |
| 제목 |
Preparation of Superhydrophobic Core-Shell Nanoparticles Synthesized by Thiol-Lactam Initiated Radical Polymerization |
| 초록 |
Superhydrophobic Core-shell nanoparticles(CSNPs) were synthesized by TLIRP. SiO2 nanoparticles (SNs) and fluoroalkyl polymer chains were used to provide two main requirements, surface ruoughness and low surface energy, for superhydrophobic surfaces. SNs were synthesized by Stober method and then the surface of the SNs was modified with (3-mercaptopropyl) trimethoxysilane which were used as seeds in polymerization in the presence of butyrolactam. The core-shell structures were observed by TEM. The peaks of CH2 (4.26 and 2.56 ppm) in the poly(heptadecafluorodecyl methacrylate) and the peak of CH3 (3.53ppm) in the poly(methyl methacrylate) appeared in 1H-NMR spectra. The results show that the CSNPs were successfully prepared by TLIRP. The maximum water and oil contact angles of coated glass with CSNPs were 166.4° and 117.2° respectively. The silica content in CSNPs affects the wettability of the coating surface owing to roughness caused by core SNs. |
| 저자 |
이지영1, 고원건2, 박인1
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| 소속 |
1한국생산기술(연), 2연세대 |
| 키워드 |
core-shell; thiol-lactam initiated radical polymerzation; superhydrophobic
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| E-Mail |
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