화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터)
권호 23권 2호, p.2441
발표분야 지속가능한 사회를 위한 고분자 기술 심포지엄(고분자부문위원회)
제목 Controlled 3D Network Structure of Gyroid Structures using High-Molecular-Weight Block Copolymer Self-assembly
초록 Materialization of well-defined nanostructures has currently been a challenge in response to the increasing demands for high-performance applications such as bio-sensors, water filtration, and nanoscale replication. In this study, a feasible approach to the direct development of gyroid (GYR) nanostructure was proposed using high-molecular-weight block copolymer (BCP) (Mn > 250 kg/mol) of polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA). The morphological transition to GYR were successfully produced during the solvent vapor annealing (SVA) process due to the unique composition (ϕPS = 0.640 ~0.660) of the BCPs. This result suggests its feasible structural tunability to the GYR structure, which would open the possible avenues applicable to other affordable materials.
저자 류두열1, 김영식1, 유필진2, 허수미3, 박성민1
소속 1연세대, 2성균관대, 3전남대
키워드 Block copolymer; Gyroid; High-Molecular-Weight; Membrane
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