| 학회 |
한국공업화학회 |
| 학술대회 |
2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO)) |
| 권호 |
25권 1호 |
| 발표분야 |
포스터-에너지저장·변환 |
| 제목 |
Perfluorocyclobutyl-containing multiblock copolymer with maximized hydrophilic/hydrophobic phase separation |
| 초록 |
Partially fluorinated perfluorocyclobutyl-containing hydrophobic oligomer and highly sulfonated poly(phenylene sulfide sulfone) hydrophilic oligomer were synthesized to multiblock copolymer. The well-developed hydrophilic/hydrophobic phase separation was observed in TEM image and in SAXS analysis. Membranes were thermally annealed at low temperature which led to enhanced connectivity of proton conducting channel. The adhesion strength against Nafion was 32.74 mN cm-1, suggesting strong interfacial compatibility in membrane electrode assembly. Fuel cell performance was 1.1346 A cm-2 (100% RH, 65 oC) at 0.6 V, and humidity (wet/dry) cycling test was maintained for 8080 cycles. |
| 저자 |
안수민1, 김태형1, 이종찬2, 홍영택1, 김태호1
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| 소속 |
1한국화학(연), 2서울대 |
| 키워드 |
hydrophilic/hydrophobic phase separation; perfluorocyclobutyl; fuel cell
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| E-Mail |
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