| 학회 |
한국공업화학회 |
| 학술대회 |
2009년 봄 (04/15 ~ 04/17, 호텔인터불고(대구)) |
| 권호 |
13권 1호 |
| 발표분야 |
고분자 |
| 제목 |
Study on controlled free-radical polymerization of adamantyl-substituted methyl methacrylates in the presence of 2-cyanoprop-2-yl 1-dithionaphthalate |
| 초록 |
Reversible addition-fragmentation chain transfer (RAFT) polymerization of 3-hydroxy-1-adamantyl methacrylate (HAdMA) and 2-ethyl-2-adamantyl methacrylate (EAdMA) were performed using 2-cyanoprop-2-yl 1-dithionaphthalate (CPDN) as a chain transfer agent. HAdMA exhibited controlled polymerization characteristics. When the same polymerization conditions were applied to EAdMA, methacrylic acid originated from the decomposition of EAdMA was observed. |
| 저자 |
이원기1, 차상호1, 손해성1, 이종찬1, 김명선2, 윤효진2, 백세경2, 김수경2, 함지윤2, 김영호2, 채승기2, 이준경3, 이재우3, 김재현3
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| 소속 |
1서울대, 2(주)삼성전자, 3(주)동진쎄미켐 |
| 키워드 |
RAFT; living radical polymerization; adamantane; methyl methacrylate
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| E-Mail |
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