초록 |
We first examined both room temperature ionic liquid (RTIL)-induced shape formation mechanism and nano-confinement effect induced by intermolecular interactions, employing 2D IR COS. This method offers a new way to interpret highly complex, veiled systems such as the formation mechanism of nanoparticles, biomineralization, self/supramolecular assembly, and nano-confinement. The tune in the molecular structures, morphologies, and phases of nanohybrids via hierarchical transformation is of prime importance in designing the nanostructures of functional materials as well as expanding the gallery of nanohybrids for applying nanopowder to a fixed bed in separation and thin film to a proton conductor in an electrochemical device. |