| 학회 |
한국화학공학회 |
| 학술대회 |
2018년 가을 (10/24 ~ 10/26, 대구 EXCO) |
| 권호 |
24권 2호, p.1621 |
| 발표분야 |
에너지 환경(Energy and Environment) |
| 제목 |
Synthesis of new benzothiadiazole based small molecules for the fabrication of organic solar cell |
| 초록 |
In this work, a new organic chromophore of donor-acceptor-donor (D-A-D) type containing 2,1,3-benzothiadiazole as the electron-withdrawing core and dimethoxyphenyl as electron-donating terminal groups (OMeBTD) was synthesized using palladium-catalyzed suzuki coupling reactions for the efficient solution-processed bulk-heterojunction (BHJ) small molecule organic solar cells (SMOSCs). The synthesized OMeBTD exhibited good optical parameters and suitable HOMO/LUMO values of -5.73 eV and -3.14 eV, respectively. The fabricated SMOSCs of configuration ITO/PEDOT:PSS/OMeBTD:PC60BM (1:4, w/w)/Au showed a power conversion efficiency (PCE) of ~1.98% with the short circuit current (JSC) of ~10.46 mA/cm² and the open-circuit voltage (VOC) of ~0.622V. The reasonable JSC and VOC of the devices might be attributed to promising absorption, emission as well as the electrochemical properties due to the presence of benzothiadiazole as strong electron-withdrawing and dimethoxyphenyl unit as electron-acceptor. |
| 저자 |
피자히라미아, 신형식, 사디아, 나 짐, 압둘라, 샤바즈
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| 소속 |
전북대 |
| 키워드 |
에너지 환경 |
| E-Mail |
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| 원문파일 |
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