화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2016년 봄 (04/06 ~ 04/08, 대전컨벤션센터)
권호 41권 1호
발표분야 기능성 고분자
제목 The preparation and characterization of polysaccharide hydrogels using epichlorohydrin or citric acid as crosslinkers
초록 Carboxymethyl cellulose(CMC) is a highly water-soluble anionic polysaccharide widely used in pharmaceuticals, as an emulsifying agent, and in cosmetics. Starch is widely used in different fields such as food, environmental-friendly plastics, and medicine due to its low cost, biodegradability, and renewability. In this study, hydrogels were prepared by chemical reaction of CMC/starch aldehyde blends with crosslinker. Prior to the reaction, starch was oxidized by sodium periodate. By this process, The hydroxyl groups, primarily at C-2, C-3, and C-6 positions, were transformed to aldehyde groups. The polysaccharide blends were crosslinked by epichlorohydrin(ECH) or citric acid. The structure of the hydrogel was established using FT-IR spectroscopy. Scanning electron microscopy was also carried out to study the surface morphology of the hydrogel. Finally, the effects on swelling behavior of the hydrogel by crosslinker variations were studied.
저자 이정민, 노현규, 박수희, 강현정, 김명욱, 박종신
소속 서울대
키워드 Polysaccharides; Starch aldehydes; Citric acid; ECH; Hydrogels
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