화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 (특별세션) 화학공정 성과발표회_C1 가스 리파이너리 사업단
제목 Direct methane dehydroaromatization on metal supported zeolite catalyst: Effects of oxygenate co-feeding
초록 Natural gas and biomass represent non-conventional hydrocarbon feedstocks that ultimately require either dehydrogenation or deoxygenation for the synthesis of commodity chemicals and fuels. Co-processing of methane and biomass would enable the synthesis of fuels with a greater degree of saturation compared to those produced from methane or biomass alone. Methane dehydroaromatization (MDA) represents a direct route for methane activation to produce aromatics and hydrogen. In this work, co-processing of methane and oxygenates to couple deoxygenation and dehydrogenation reaction sequences was accomplished using Mo/HZSM-5 catalyst. The effect of oxygenates co-feeding on the product formation rate, selectivity and catalyst stability in the MDA reaction will be presented. The catalyst structure and active species will be characterized by a number of complementary techniques, allowing correlation of the catalytic behavior as a function of the physicochemical properties of the catalysts.
저자 홍도영
소속 한국화학(연)
키워드 Methane dehydroaromatization; BTX; Biomass; co-processing
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