화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2021년 봄 (04/21 ~ 04/23, 부산 BEXCO)
권호 27권 1호, p.112
발표분야 고분자
제목 A biologically muscle-inspired polyurethane with super-tough, thermal reparable and self-healing capabilities for stretchable electronics
초록 Polymeric elastomers play an increasingly important role in the development of stretchable electronics. A highly demanded elastic matrix is preferred to own not only excellent mechanical properties, but also additional features like high toughness and fast self-healing. Here, we synthesized a polyurethane (DA-PU) with donor and acceptor groups alternately distributed along the main chain to achieve both intra-chain and inter-chain D-A self-assembly, which endow the polyurethane with toughness, self-healing and, more interestingly, thermal repair, like human muscle. In detail, DA-PU exhibited an remarkable mechanical performance, anti-fatigue and anti-stress relaxation properties as manifested by cyclic tensile and stress relaxation tests, respectively. Even in case of large strain deformation or long-time stretch, it could almost completely restore to original length by thermal repair at 60℃ in 60s. The self-healing speed of DA-PU could be 1.0 ~ 6.15 μm/min from 60℃ to 80℃. At last, a stretchable and self-healable capacitive sensor was constructed and evaluated to prove that DA-PU matrix could ensure the stability of electronics even after critical deformation and cut off.
저자 WUBIN YING1, Ruoyu Zhang2, Jin Zhu3, 이경진3, 김도환4
소속 1Ningbo Institute of Materials Technology and Engineering, 2Chinese Academy of Science / 한양대, 3Chinese Academy of Sciences, 4충남대
키워드 첨단고분자
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