화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터)
권호 15권 1호, p.1021
발표분야 촉매 및 반응공학
제목 The studies on catalytic wet peroxide oxidation processto remove1,4-Dioxane
초록 1,4-Dioxane causes liver damage and kidney failure, has been known to be carcinogenic to animals, and is a potential carcinogen for humans and, hence, is classified as a hazardous waste and a priority pollutant.1,4-Dioxane has a highly symmetric chemical structure, and is known to be extremely refractory against biological decomposition. Accordingly conventional biological wastewater treatment method such as activated sludge method is not appropriate for the successful treatment of 1,4-dioxane.
Cu wire catalystwas highly reactive toward catalyticwet peroxide oxidation of the highly refractory 1,4-dioxane. Complete removal of 1,4-dioxane could be achieved with the catalyst. 1,4-Dioxane was primarily transformed into intermediates of Ethylene glycol diformate, oxalic acid, formic acid, formaldehyde and acetaldehyde they were formed in a sequential procedure. The Cu wire catalyst was also highly stable against deactivation during the reaction.
저자 김둘선, 김태한, 이영경, 조미정, 레넥투안, 이동근
소속 경상대
키워드 Catalytic wet peroxide oxidation; Cu wire; 1; 4-dioxane
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