화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 기능성 고분자
제목 Eco-friendly Synthesis of Photosensitive Poly(Amic Acid) Salt as Patternable Polyimide Precursor
초록 Polyamic acid salt (PAAS) paired with photo cross-linkable organic bases is one class of photosensitive polyimides (PSPIs), which dissolve in the water and can be cross-linked under UV light. The PAAS is converted to polyimide (PI) at relatively a low temperature and simplifies the patterning process, which allows us to utilize them as the insulation and packaging material in the semiconductor. The preparation route for PAAS is a multi-step reaction including the synthesis of poly(amic acid) (PAA) in an organic solvent followed by the salt-forming process using tertiary amines, which causes an increase in cost and environmental pollution. In here, we suggest the one-step and green synthesis of PAAS using water as the solvent. We also demonstrate the preparation of patterned polyimide with tens of micrometer through the lithographic process followed by the thermal treatment.
저자 이효은1, 박종민2, 김윤호1, 김진수1, 조정호1, 원종찬2
소속 1한국화학(연), 2연세대
키워드 eco-friendly synthesis; photosensitive poly(amic acid) salt; patternable polyimide precursor; photosensitive polyimide
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