| 학회 |
한국화학공학회 |
| 학술대회 |
1997년 가을 (10/24 ~ 10/25, 충남대학교) |
| 권호 |
3권 2호, p.3669 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
H3PMo12O40 -이 혼성된 고분자 필름촉매의 특성 및 산 촉매 작용 |
| 초록 |
PMo-imbedded PSF film catalysts were prepared using MC or MB by membrane technology and they were used as fixed bed catalysts for the vapor phase ethanol dehydration and MTBE decomposition reaction. The film catalysts were non-porous film catalysts. The film catalyst activity for the MTBE decomposition is much higher than that of bulk PMo. It was found that PMo was physically blended with PSF and PMo was finely distributed throughout PSF film. It was also observed that PMo formed a pseudo-liquid phase in the film catalysts. PMo-PSF-MC and PMo-PSF-MB showed a remarkably enhanced catalytic activity for the acid-catalyzed reactions compared to bulk PMo. It was summarized that the enhanced acid catalysis of PMo-PSF-MC and PMo-PSF-MB was due to the fine distribution of PMo through entire film catalysts as a physical blending. The relatively neutral property of MC (or MB) was also responsible for the enhanced acid catalysis of those film catalysts. The pseudo-liquid phase behavior of PMo also played an important role on the enhanced acid catalysis of these film catalysts
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| 저자 |
임성수, 박교익, 최준선, 송인규, 이화영
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| 소속 |
서울대 화공과 |
| 키워드 |
Heteropolyacid; polymer; acid catalysis; blending; pseudo-liquid phase behavior
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| E-Mail |
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| 원문파일 |
초록 보기 |
