| 학회 | 한국공업화학회 |
| 학술대회 | 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 19권 2호 |
| 발표분야 | 정밀화학_포스터 |
| 제목 | Coupling and nitration study of azole compounds |
| 초록 | High energy density materials (HEDMs) on the base nitroazoles are widely used for not only military purposes but also civilian applications. It has been reported that polynitroazoles have high heat of formation, density, and low sensitivity toward friction, impact and thermal shock. Therefore they are expected to be backbones of HEDMs and 3,4,5-trinitropyrazole(TNP) derivatives are representatives which have been actively studied recently. The bridged polynitroazole compounds are promising structures to improve the explosive performances because they are expected to have high density and positive oxygen balance. However N-N’-alkyl-bridged nitroazoles are rarely studied except for N-N’-ethyl-bridged azoles. Our group has been studied synthesis methods of N-N’-alkyl-bridged nitroazole compounds and their further nitrated derivatives as basic skeletons for potential HEDMs. Herein, we demonstrate a synthesis of N-N’-alkyl-bridged nitroazoles and their nitration experiment results. |
| 저자 | 김영규1, 김진석2, 오정환1, 이병일1, 김남태1 |
| 소속 | 1서울대, 2국방과학(연) |
| 키워드 | Azole; Coupling; Nitration; High energy density materials(HEDMs) |
