화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 고분자구조 및 물성
제목 Water Permeability of PS-b-PMMA Block Copolymer films
초록 Spontaneous microphase separation of the block copolymer (BCP) in the thin film geometry leads to preferential orientation of microdomain arrays or random orientation. A parallel orientation of cylindrical microdomains would be favourable with preferential interactions of the substrate with one block, and/or the large difference in surface energies of the two blocks, while the perpendicular orientation is achievable by controlling the interfacial and surface interactions. We investigated water permeability of cylinder-forming polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) films using neutron reflectivity (NR). The microdomain orientation dependence on water permeability will be discussed in terms of density distribution of each block.
저자 김상우1, 안형주2, 박성민1, 류두열1
소속 1연세대, 2포항가속기(연)
키워드 Water permeability; Block copolymer self-assembly; Microdomain orientation
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