화학공학소재연구정보센터
학회 한국재료학회
학술대회 2011년 봄 (05/26 ~ 05/27, 제주 휘닉스 아일랜드)
권호 17권 1호
발표분야 B. Nanomaterials and Processing Technology((나노소재기술)
제목 Binder-free and Full Electrical-Addressing Free-standing Nanosheets with Carbon Nanotube Fabrics for Electrochemical Applications
초록 As the old saying ‘nothing is complete unless you put it in final shape’, although nanosheets (NSs) are a promising functional building block for various electrochemical applications, their true value cannot be realized until they are well woven into electrical conducting materials. As an effort to determine their ideal shape, in this study, a unique manufacturing route to build a layer-by-layer (LBL) structure of two-dimensionally ordered, free-standing β-nickel hydroxide nanosheets (β-NHNSs) that are fully electrically addressed with single-wall carbon nanotube fabrics was demonstrated, and its capabilities were verified through a comparative study on the differences between a simple bulky and LBL-structured electrochemical cathode, representing two extreme cases. The LBL-structured cathode showed a discharging current peak that was 25 times larger than the bulky structured one measured in cyclic voltammetry, which implies that the LBL structure is near an ideal electrode configuration for NS-based electrochemical applications.
저자 이태일1, 제갈종필1, 최지혁1, 최원진2, 이민정1, 오진영1, 김광범1, 백홍구1, Younan Xia3, 명재민1
소속 1연세대, 2한국화학(연), 3Washington Univ. St Louis
키워드 Nanosheets; Carbon nanotube; Electrochemical; Layer-by-layer
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