초록 |
Chiral inorganic nanostructures have triggered tremendous interests due to their potential applications and technological prospects. Even though various strategies have been reported for fabricating chiral inorganic nanostructures, the complex processes and expense remain formidable challenges to realize mass production and large-area fabrication with simple and cost-effective processes. In this study, we suggest a general protocol for the fabrication of chiral inorganic nanostructures based on achiral templates consisting of block copolymer inverse micelles and racemic mixtures. In-situ formed inorganic nanoparticles (NPs) of Au NPs, Ag NPs, Pd NPs, and TiO2 NPs in the micellar cores show strong chiroptical properties, although chiral reagents and scaffolds were not involved in any step. Our design concept pinpoints forwarding steps to construct an extended library of viable chiral inorganic nanostructures, ensuring a substantial development in the field of chiroptics. |