학회 | 한국고분자학회 |
학술대회 | 2003년 가을 (10/10 ~ 10/11, 부경대학교) |
권호 | 28권 2호, p.318 |
발표분야 | 고분자 합성 |
제목 | Dispersion polymerization in supercritical carbon dioxide with novel fluorinated polymers |
초록 | Recently, we synthesized novel fluorinated polymers consisting of hydrophilic oxyethylene backbone and fluorinated side groups using polymer analog reactions. These fluorinated polymers were found to have double layered structures and very low surface energies. In this presentation, we will report the dispersion polymerization of methyl methacrylate and 1-vynil-2-pyrrolidone in supercritical carbon dioxide using the fluorinated polymers. These fluorinated polymers have shown the appreciable solubility in supercritical carbon dioxide and works as a surfactant due to the amphiphilicity arised from the CO2 |
저자 | 김병각, 이종찬, 배원, 신보현, 김화용 |
소속 | 서울대 |
키워드 | dispersion polymerization; supercritical carbon dioxide |