| 학회 |
한국화학공학회 |
| 학술대회 |
1999년 봄 (04/23 ~ 04/24, 성균관대학교) |
| 권호 |
5권 1호, p.641 |
| 발표분야 |
열역학 |
| 제목 |
전해질을 포함하는 크러스레이트 용액의 생성 속도론 |
| 초록 |
Experimental data on the formation kinetics of carbon dioxide hydrate from gaseous carbon dioxide were obtained at several temperatures from 273.15 to 277.15 K and at three pressures of 3.4, 3.0 and 2.5 MPa. In addition, to determine the electrolyte effect on the formation kinetics experimental data of carbon dioxide amount consumed during the hydrate formation in aqueous NaCl solutions were also obtained at 3.0 MPa. The NaCl concentrations in aqueous liquid were 1 and 5 mass %. The kinetic model developed in this work was based on the adsorption theory and had only one adjustable parameter of the formation rate of carbon dioxide hydrate. The difference between the fugacity of the dissolved gas and the H-Lw-V three-phase equilibrium fugacity was used as the pressure effect term in this model. The proposed model was found to describe the experimental data very well. It was indicated that the presence of electrolytes could inhibit the formation rate of carbon dioxide hydrate considerably.
|
| 저자 |
전문균, 서유택, 이흔
|
| 소속 |
한국과학기술원 화학공학과 |
| 키워드 |
Carbon dioxide; Hydrate; Kinetics; Nacl
|
| E-Mail |
|
| 원문파일 |
초록 보기 |
