| 학회 |
한국고분자학회 |
| 학술대회 |
2005년 봄 (04/14 ~ 04/15, 전경련회관) |
| 권호 |
30권 1호, p.547 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Phase coherence upon heating in diblock copolymer films |
| 초록 |
We have performed the mean field calculation on the thin films of diblock copolymers that microphase separate upon heating in the bulk. The thin films are confined between two different surfaces. The density profiles of block components were obtained through the film thickness as a function of temperature. The decay lengths of the observed surface ordering and phase coherence transitions upon heating were determined from the profiles. The recently developed compressible Landau analysis has been applied to the copolymer films to interpret the experimental reflectivity results. It was shown that specific interactions and finite compressibility are the two major issues concerning the observed behavior for the copolymers. |
| 저자 |
조광수1, 조준한2, 김은경2, 백미라2, 신관우3
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| 소속 |
1경북대, 2단국대, 3광주과학기술원 신소재공학과 |
| 키워드 |
block copolymer; thin film; mean field
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| E-Mail |
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