화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 고분자구조 및 물성
제목 3-D Sub-Nano Ordering from Poly(2-vinylpyridine)
초록 3-D molecular-level ordering is an important and challenging objective of current research in materials chemistry and physics. It can improve the efficiency of systems or generate entirely new types of systems containing functionalities that were previously unattainable. Self-assembly is emerging as an elegant and powerful approach to fabricating nano-structured materials. [1-4] However, controlling the precise arrangement of m olecules on the molecular scale is most demanding due to the difficulty in making such small structures. [5,6] Molecular-level self recognition and organization during the chemical reaction of poly(2-vinylpyridine) (P2VP) with 1,4-dibromobutane influence the tacticity of P2VP, leading to the sub-nanometer level molecular ordering of pyridine moieties in the polymer chain. This long range hexagonal organization switches P2VP from an amorphous to a 3-D metallic polymer.
저자 서호빈1, 이재석2, Mohammad Changez1, 고행덕2, 강남구3, 김진규1, 김윤중2, Sasidher Samal1
소속 1광주과학기술원, 2신소재공학부, 3나노바이오재료전자공학과(WCU)
키워드 ordering; 2-vinylpyridine
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