화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 봄 (04/07 ~ 04/09, 대전컨벤션센터)
권호 46권 1호
발표분야 기능성 고분자
제목 In-situ diepoxidesiloxane-based polymer electrolyte for lithium-ion batteries
초록 The safety issues of lithium-ion batteries caused by liquid organic electrolytes have been driving individuals to seek safer electrolytes. A series of diepoxide siloxane-based polymer electrolytes have been fabricated and characterized. Herein, an in-situ crosslinking strategy was used to reduce the interface impedance between electrodes and polymer electrolyte. The obtained polymer electrolyte shows high ionic conductivity (1.16×10−4 S cm−1 at room temperature) and electrochemical window up to 4.0 V (vs. Li/Li). Meanwhile, LiCoO2/polymer electrolyte /Li shows a specific discharge capacity of 129 mAh g−1 at 0.1 C. this work indicates that polydiepoxidesiloxane crosslinked by in-situ strategy yields a high-performance polymer electrolyte for future polymer electrolyte lithium-ion batteries.
저자 진레이, 류태욱, 윤수진, WEI ZHANG, 장기석, 임현민, 김환기, 장호현
소속 건국대
키워드 lithium-ion batteries; diepoxidesiloxane; in-situ; polymer electrolytes
E-Mail