화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 환경에너지_포스터
제목 Correlation Studies between Pore Structure and Electrochemical Performance of Activated Polymer-based Hard Carbon
초록 In this study, activated polymer-based hard carbon (APHC) was first prepared using CO2 activation. Then electrochemical measurements of APHC-applied electrodes were used to evaluate these electrodes for application to electric double-layer capacitors. The APHCs were prepared under different conditions of activation temperature and time. APHC-10-40 and APHC-10-50 showed good textural properties (specific surface area: 2440 and 2210 m2/g, mesopore fraction: 43.5 and 63.1%, respectively). These properties were observed using the N2 /77 K adsorption isotherms and APHC have favorable pore structures for ion adsorption in electrolytes. APHC-10-50 showed 117 F/g of specific capacitance in propylene carbonate (PC), but only 106 F/g in acetonitrile (AcN), very different from APHC-10-40 (77 F/g in PC and 120 F/g in AcN).
저자 백진1, 김병주2
소속 1한국탄소융합기술원 / 전북대, 2한국탄소융합기술원
키워드 hard carbon; textural properties; mesopore; electrollyte
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