화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 봄 (04/12 ~ 04/13, 제주 ICC)
권호 32권 1호
발표분야 고분자 구조 및 물성
제목 Phase Behavior of Mixture of Symmetric PS-PnPMA Block Copolymers and Homopolymers
초록 The phase diagrams for mixtures consisting of symmetric polystyrene-block-poly (n-pentyl methacrylate) copolymer (PS-PnPMA) and PS (or PnPMA) homopolymers with various molecular weights are presented. The lower disordered-ordered transition (LDOT) and upper ordered-disordered transition (UODT) temperatures of mixtures were determined by polarized optical microscopy, depolarized light scattering and small angle x-ray scattering. The LDOT decreases but UODT increases with increasing amount of PS. Microdomains of the mixtures were examined by transmission electronic microscopy.
저자 김은영, 김진곤
소속 포항공대
키워드 closed-loop phase behavior; lower disordered-ordered transition (LDOT); upper ordered-disordered transition (UODT); transition behavior of block copolymer
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