화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1622
발표분야 에너지
제목 Long Range ElectronTransfer over Graphene-based Catalyst for High Performing Oxygen Reduction Reactions: Importance of Size, N-doping, and Metallic Impurities
초록 N-doped carbon materialsare considered as next-generation oxygen reduction reaction (ORR) catalysts forfuel cells due to prolonged stability and low cost. However, the underlyingmechanism of these catalysts is barely identified, preventing the rationaldesign of high performing catalysts. Here, we show that the first electron istransferred into O2 molecules at the outer Helmholtz plane (ET-OHP)over a long range. Based on the ET-OHP mechanism, the location of the electrode potential dominantly characterizes the ORR activity.
저자 정민욱, 최창혁, 임형규, 박종철, 신혜영, 우성일
소속 KAIST
키워드 polymer electrolyte membrane fuel cell; oxygen reduction reaction; graphene
E-Mail
VOD VOD 보기
원문파일 초록 보기