화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1694
발표분야 에너지
제목 In-situ N-doped graphene/Li4Ti5O12 nanocomposites for lithium battery node
초록 The lower electrical conductivity of the LTO limits the rate capability at higher current rates. Recently, conducting materials such as carbon coating, graphene or nitridation has been applied to increase the electrical conductivity and electrochemical stability of the LTO. Recent reports suggested that the hybrid material of graphene/LTO exhibited an excellent electrochemical stability in lithium battery due to an improved electrical conductivity of LTO. Herein, we report on the preparation of in-situ N-doped G/LTO nanocomposites using diethylenetriamine (DETA) as a reducing agent as well as N-dopant to graphene sheets. The N-doping increases the electrical conductivity and ionic diffusion of the electrode. The effect of reduction and N-doping on the graphene oxide was systematically studied at gradual addition of DETA. The nanocomposite was fabricated as lithium battery anode and results were compared with pristine LTO and RGO/LTO prepared in the absence of DETA.
저자 Nguyen Thi Bich Huong, Balasubramaniyan, 정진석
소속 울산대
키워드 N-doping; DETA; graphene/LTO; anode material
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