| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Synthesis and properties of sulfonated poly(arylene sulfone)s containing multiphenyl structure without ether linkage by carbon-carbon coupling nickel catalyzed polymerization |
| 초록 |
The synthesis of poly(arylene sulfone)s, their functionalization with sulfonic acid groups, and the measurement of apposite parameters for PEMs are described. The polymers were prepared by Ni-catalyzed homocoupling reaction of multiphenyl monomer and 4,4-chlorophenyl sulfone. These polymers have no ether linkage on polymer backbone that was not attacked by nucleophiles (H2O, hydrogen peroxide, hydroxide anion and radical). And sulfonic acid groups were introduced by sulfonation reaction with chlorosulfonic acid. All these membranes were casted from dimethylacetamide (DMAc). The structure properties of the synthesized polymers were investigated by 1H-NMR spectroscopy and FT-IR. The membranes were studied by ion exchange capacity (IEC), water uptake, and proton conductivity. These membranes deterioration test was performed by Fenton reagent, and compared with normal sulfonated poly(ether sulfone)s and Nafion. |
| 저자 |
최성영, 임영돈, 이순호, Hossain, 이현철, 임진성, 김환기
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| 소속 |
건국대 |
| 키워드 |
PEMFC; proton conductivity; C-C coupling; nickel catalyst; Fenton test
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| E-Mail |
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