화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 고분자구조 및 물성
제목 Temperature dependence of d-spacing and Transition behavior of PS-b-PMMA/PS homopolymer
초록 In this study, we investigated the temperature dependence of d-spacing and transition behavior of polystyrene-b-poly(methyl methacrylate) (PS-b-PMMA)/PS homopolymers using small-angle x-ray scattering (SAXS) analysis, where the various molecular weight (or chain length) of PS homopolymer. The d-spacing and order-to-disorder transition (ODT) by addition of PS homopolymers were significantly influenced by the PS molecular weight. This variation can be attributed to a competing interaction between the thermal swelling effects of the microdomains with homopolymers and the decrease in the chain stretching between the two block components.
저자 안형주, 이용훈, 이호연, 박성민, 류두열
소속 연세대
키워드 block copolymer; phase behavior; order-to-disorder transition
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