| 학회 | 한국화학공학회 |
| 학술대회 | 2016년 가을 (10/19 ~ 10/21, 대전컨벤션센터) |
| 권호 | 22권 2호, p.1862 |
| 발표분야 | 에너지 |
| 제목 | Thermal and Catalytic pyrolysis of Citrus Peel |
| 초록 | In this study, thermal and ex-situ catalytic pyrolysis of citrus peel was investigated using a tandem micro reactor-GC/MS. Thermal pyrolysis at 500oC produced large amounts of oxygen containing pyrolyzates such as alcohols, ketones, and furans. The oxygen containing pyrolyzates were efficiently upgraded into value added aromatic compounds such as benzene, toluene, ethylbezene, xylenes, naphthalene, and methyl naphthalene by applying catalytic upgrading at 600oC. Compared to wood powder, citrus peel produced the larger amounts of aromatics over HZSM-5 (SiO2/Al2O3: 23). Among various kinds of catalyst tested in this study, HZSM-5 (23) and HBETA (25) showed the highest performance for the formation of aromatic hydrocarbons. Meanwhile, HBETA (25) produced the larger amounts of polyaromatic hydrocarbons and deactivated faster than HZSM-5 (23) due to the larger amount coke formation during sequential catalytic pyrolysis reaction of citrus peel. Acknowledgement : This research was supported by Hallym University Research Fund, 2016 (HRF-201607-012). |
| 저자 | 김영민1, 이형원2, Atsushi Watanabe3, 한태욱1, 이보람1, 김승도1, 박영권2 |
| 소속 | 1한림대, 2서울시립대, 3Frontier Laboratories Ltd |
| 키워드 | 에너지 전환 |
| VOD | VOD 보기 |
| 원문파일 | 초록 보기 |
