| 학회 |
한국화학공학회 |
| 학술대회 |
2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터) |
| 권호 |
19권 1호, p.1088 |
| 발표분야 |
신진연구자 심포지엄 |
| 제목 |
Epoxidation of Vegetable Oils Using the Heterogeneous Catalysis, Amorphous Ti-SiO2 |
| 초록 |
The epoxidation reaction of the vegetable oil derivative methyl oleate with tert-butyl hydroperoxide in the presence of amorphous Ti-SiO2 catalysts prepared by different methods using various silica sources was carried out. The reaction conditions were optimized. The relation between the properties of the catalysts such as BET surface area as well as titanium dispersion and the catalytic performance was in focus of the investigation. Based on the catalytic results in small batch reactors, the reaction was scaled up in a larger 4 L batch-reactor. Similar conversions and selectivities were obtained in comparison with the small scale experiments. |
| 저자 |
김경훈 |
| 소속 |
POSCO 엔지니어링연구센터 |
| 키워드 |
epoxidation; methyl oleate; tert-butyl hydroperoxide; amorphous Ti-SiO2
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| E-Mail |
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| VOD |
VOD 보기 |
| 원문파일 |
초록 보기 |
