| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
고분자가공/복합재료- 미래 자동차용 고분자소재 최신기술 동향 |
| 제목 |
Hydrogen Bond-Triggered, Surfactant Free Synthesis of Mesoporous, Silica-Polymer Nanostructured Materials for the Remidation of Environmental Pollutants |
| 초록 |
We have developed a facile strategy for the synthesis of two mesoporous silica i.e. rambutan-like MSNPs (R-MSNPs) and hollow MSNPs (H-MSNPs) using a surfactant-free strategy at room temperature a high surface area (up to 1025 m2/g). A cationic polymer (PEI) with various MW (2kd to 750 kd) were used. The particle sizes were uniform with tunable surface structures by varying the loading volume ratio of Si/PEI (1:1to1:5), reaction time. We have tested the removal of pollutants in environmental remediation applications. Exhibited promising performances for the removal of heavy metal with a high adsorption capacity (qe), e.g. Pb=343.304 mg/g; Hg=289.2644 mg/g. In addition, synthesized materials have been applied for the efficient disposal of waste water containing bulky dye molecules like methyl orange with a high absorption rate ＞95% and removals of toxic MC-YR over 97%. Also high loading capacity of gold-NPs offered excellent catalytic activities for the reduction of nitrophenol (NPh). |
| 저자 |
샤히눌1, 이하진2, 최원산3
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| 소속 |
1KBSI, 2kbsi, 3한밭대 |
| 키워드 |
Hydrogen bonding; Mesoporous silica; Heavy metal removal;
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| E-Mail |
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