| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Iodine vapour doped polyaniline nanoparticles as a catalytic counter electrode in dye sensitized solar cells |
| 초록 |
Polyaniline (PANI) dispersions consisting of 10-20 nm sized nanoparticles were prepared by oxidation with ammonium peroxydisulfate (APS) in sodium dodecyl sulfate (SDS) micellar solutions. A methanol-based colloidal dispersion containing 5 wt% PANI was spincoated onto fluorine-doped tin oxide (FTO) glass to use as counter electrodes (CEs) in dye sensitized solar cells (DSSCs). The surface resistivity of the PANI layer on the FTO glass decreased after post-doping with concentrated Iodine vapor for 10 min. The post-doped and highly oxidized PANI allowed the electrons to move into the PANI layer readily and facilitated the electrocatalytic reaction of the I3-/I- redox couple, giving enhanced cell performance. |
| 저자 |
이영우, 이태현, 임승순
|
| 소속 |
한양대 |
| 키워드 |
Iodine vapour; polyaniline; counter electrode; dye sensitized solar cells
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| E-Mail |
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