화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 봄 (04/26 ~ 04/28, ICC 제주)
권호 23권 1호, p.677
발표분야 에너지 환경
제목 Surfactant effects in mediated electrocatalytic reduction of cinnamyl chloride by electrogenerated micelle-solubilized Co(I)(bipyridine)
초록 Surfactants are well-known to offer exciting beneficial effects in electrochemical science and technology. In the present work, effect of CTAB and TDTAB surfactant micelles was examined in the electrocatalytic reductive dechlorination of toxic cinnamyl chloride mediated by [Co(I)(bpy)3]+ in aqueous solutions. First, the surfactant aggregates were characterized by CV and RDE techniques using [Co(II)(bpy)3]2+/[Co(I)(bpy)3]+  as redox probes. The information was subsequently used to explain the differences exerted by CTAB and TDTAB surfactants on the cinnamyl chloride reduction process.
저자 G. MUTHURAMAN, K. Chandrasekara Pillai, 문일식
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