| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
20권 2호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Ethylene oxide functionalized vegetable oil based polyol for waterborne polyurethane dispersion |
| 초록 |
Due to growing concerns on environmental issues and volatile organic compounds, waterborne polyurethanes (WPUs) have drawn attentions in polymer industry. Ethylene oxide (EO) has been widely used as soft segment for the WPUs because of its hydrophilic nature. In this study, preparation of hyperbranched polyols with EO functionalities were attempted through thiol-ene click reaction between soybean oil (SO) and thiol-containing EO compounds. The resulting SO-based polyols were successfully incorporated into WPUs, exhibiting hyperbranched chain architectures. Proton nuclear magnetic resonance spectroscopy and gel permeation chromatography were employed to investigate the functionalities and structural characteristics of the EO-functionalized SO-based polyols and WPUs. Thermal and mechanical properties of the WPUs were evaluated, along with their dispersion stability behaviors. |
| 저자 |
Alagi Prakash Kallappa, 최예진, 홍성철
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| 소속 |
세종대 |
| 키워드 |
Ethylene oxide; soybean oil; thiol-ene click reaction; polyol; waterborne polyurethane
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| E-Mail |
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