| 학회 |
한국고분자학회 |
| 학술대회 |
2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관) |
| 권호 |
34권 2호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Synthesis of Poly(N-methyl-2-thiophenylfulleropyrrolidine) derivatives for Dye-Sensitized Solar Cell. |
| 초록 |
In this study, we synthesized N-methyl-2-fulleropyrrolidine (MFP) substituted thiophene groups and its copolymers to apply on DSSC devices as a charge transfer material in the electrolyte of DSSC, as poly(MFP-co-3HT), poly(MFP-co-3DT) and poly(MFP-co-3TA) was synthesized by the reaction of MFP with 3-hexylthiophene (3HT), 3-dodecylthiophene (3DT), 3-thiopheneacetic acid (3TA) in the presence of FeCl3 , respectively. The chemical structures and properties of synthesized copolymers were characterized by 1H-NMR, UV-Vis spectroscopy, Cycilc Voltametry and Gel Permeation Chromatography. The DSSC devices were fabricated and their photovoltaic performances were measured by using solar simulator under AM 1.5 illumination. The active area was 0.36 cm2. |
| 저자 |
이수빈1, 이승민1, 김기현1, 조상은1, 박성해1, 김영근1, 장성일2, 김미라1, 이진국1
|
| 소속 |
1부산대, 2주식회사 솔켐 |
| 키워드 |
dye-sensitized solar cells; fullerene derivatives; polythiophene
|
| E-Mail |
|
