화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아)
권호 17권 2호, p.1179
발표분야 고분자
제목 Enhanced dispersion of carbon nanotubes using amphiphilic PVC-g-POEM graft copolymer
초록 Multi-walled carbon nanotubes (MWCNTs) drawattention as promising materials because of their excellent electricaland mechanical properties. Nevertheless, irregular aggregations of MWCNTs resulted from intrinsic attractive interactionbetween MWCNTs offers a challenge to their use invarious applications. Here, we present a facile method to disperseMWCNTs in a polar solution using a graft copolymer, poly(vinychloride)-graft-poly(oxyethylene methacrylate), PVC-g-POEM.The graft copolymer was synthesized via atom transfer radicalpolymerization (ATRP), as confirmed by gel permeation chromatography(GPC) and 1H NMR spectroscopy. The MWCNTswere uniformly dispersed in a polar solvent such as dimethylsuloxide(DMSO) by the help of PVC-g-POEM as a dispersant,owing to interaction between MWCNT and the graft copolymer, asrevealed by transmission electron microscopy (TEM) analysis.Upon removal of the solvent, free standing nano-composite membraneswith good homogeneity were obtained.
저자 서진아, 전하림, 노동규, 고주환, 김종학
소속 연세대
키워드 graft copolymer; atom transfer radical polymerization; carbon nanotubes; nanocomposite
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