| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis and Characterization of Polyurethane Ionomers Based On Pyrrolidinium Ionic Liquid Monomers |
| 초록 |
Novel polyurethane ionomers containing pyrrolidinium cations on the polymer backbone is synthesized from a dihydroxyl functionalized pyrrolidinium ionic liquid monomer and 4,4’-diphenylmethane diisocyanate (MDI). Polyurethane copolymers are also synthesized with comonomers such as polyethylene glycol(PEG) or Jeffamine® ED-900. FT-IR and 1H NMR are used to see the polymerization reaction completion and mole ratio of the ionic and non-ionic monomers in the polyurethane ionomers. The thermal properties of the all polyurethane ionomers are investigated by differential scanning calorimetry and thermal gravimetric analysis. The polyurethane ionomers with PEG4000 contain crystalline phases at room temperature, however the other polyurethane ionomers are amorphous throughout the whole measuring temperature range. The polyurethane ionomers with PEG1000 and Tf2N- anions shows ionic conductivity 1.77 x 10-2 S/cm at 120 oC. |
| 저자 |
신종찬, 이민재, 최종인
|
| 소속 |
군산대 |
| 키워드 |
Ionic liquid; Polyurethane; Polyurethane copolymer; Polyurea/urethan; PEG; Jeffamin
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| E-Mail |
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