화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2014년 가을 (10/22 ~ 10/24, 대전 DCC)
권호 20권 2호, p.1442
발표분야 미립자공학
제목 Flame Syntheised Nanostructured WO3 Thin Films for Photoelectrochemical Application
초록 Tungsten oxide is one of the most widely studied semiconductor material as photoanode for photoelectrochemcial water-splitting techonologies due to its favorable intrinsic electrochemical properties. One-dimentional (1D) nanustructured tungsten oxide has shown great potential for this application. We prepared the 1-D nanotube and nanoflower structured tungsten oxide on fluorine-doped tin oxide (FTO) glass by a simple three-step approach. Firstly, a seed layer was coated on FTO glass by spin coating. Secondly, a simple, rapid aerosol flame deposition method was utilized to fabricate 1-D W18O49 thin film, in which the tungsten wire was evaporated and oxidized in a fuel- rich flame to produce tungsten oxide vapors and to be condensed onto a colder FTO glass substrate. Followed by annealing process, these 1-D W18O49 thin films could be converted to 1-D nanostructured WO3 thin films. The morphology difference of thin films with or without seed layer was compared. Thin films structure properties were characterized by SEM, XRD and TEM. The photoelectrochemical properties of the assembled thin films with distinct morphologies were tested by IPCE measurement system.
저자 윤상혁, Ding Jinrui, 배동섭, 박수희, 김교선
소속 강원대
키워드 WO3 Thin Films; Nanotubes and Nanoflowers; Flame Synthesis; IPCE measurement; photoelectrochemical water-splitting
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