화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 유기전자소자용 소재 및 소자(분자전자소재 부문위원회)
제목 Synthesis of conjugated polymer containing 2,5-bis(3-decylthiophen-2-yl)thiazolo[5,4-d]thiazole and 2,6-[(1,5-didecyloxy)naphthalene and its solar cell properties
초록 A new alternating donoracceptor conjugated polymer, poly{(2,5-bis(3-decylthiophen-2- yl)thiazolo[5,4-d]thiazole-5,5_-diyl)-alt-(2,6-[(1,5-didecyloxy)naphthalene])} (PNTzTz) based on thiazolothiazole and didecyloxynaphthalene units was synthesized using a typical Suzuki coupling polymerization method and was explored as a donor polymer in bulk heterojunction solar cells. The polymer was characterized using differential scanning calorimetry, thermogravimetric analysis, UVVis absorption and cyclic voltammetry. Photovoltaic properties of the polymer were investigated blended with electron acceptor, [6,6]-phenyl-C61- butyric acid methyl ester (PC61BM) in the device configuration of ITO/PEDOT:PSS/PNTzTz:PC61BM/LiF/Al and shows a power conversion efficiency up to 0.99%.
저자 양우승, Pranabesh Dutta, 박한옥, 백명진, 김정석, 이연식, 이수형
소속 전북대
키워드 Donoracceptor conjugated polymer; Bulk-heterojunction polymer solar cell; Thiazolothaizole
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