화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 기능성 고분자 (포스터발표만 진행)
제목 Synthesis of Sulphonic group Modified PMO for Selectivity Metal Adsorption
초록 The modified periodic mesoporous organosilica(PMO) has the advantages of extremely high specific surface area, regular pore canal structure, and uniform distribution of organic functional groups on the pore surface. We have successfully synthesized through bissilylated urea bridged PMO and modified using chlorosulphonic acid in chloroform. Ethanol was used to lead the self-assembly process. The PMO was used for the sorption of Fe(III) in wastewater solution. The effects of solution pH, sorption time, temperature and initial metal ion concentration onto metal ions sorption have been investigated. It was characterized by Fourier transform infrared spectroscopy, Energy Dispersive X-ray Spectroscopy, Scanning electron microscope, Transmission electron microscopy and X-ray diffraction. The sorption of metal ions onto sulphonic acid modified PMO were strongly dependent on the chemical interactions and chelating effects.
저자 송현진, 이상현, 박성수, 성아름, 하창식
소속 부산대
키워드 wastewater; periodic mesoporousorganosilica; metal ion
E-Mail