화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.30, No.8, 1636-1643, August, 2013
DOI10.1007/s11814-013-0076-x  Export Citation
Thermodynamics of molecular interactions in binary mixtures containing associated liquids
Manju Rani, and Sanjeev Maken1, †
  • Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
  • 1Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology, Murthal-131 039, India
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Experimentally measured data of excess molar volumes and enthalpies at 308.15 K for binary mixtures of formamide with 1-butanol or 2-methyl-1-propanol were fitted to the Redlich-Kister polynomial equation. Thermodynamics of molecular interaction in these mixtures was discussed using Prigogine-Flory-Patterson theory, Treszczanowicz-Benson association model and Graph theoretical approach. Extent of inter-molecular H-bonding in formamide and butanol in their binary mixtures was also reflected in their molar enthalpy of association of H-bonding ΔhH0 and association constant KH calculated from Treszczanowicz-Benson association model. All the three theories predict the excess property data reasonably well.
Keywords:Excess Molar Enthalpy;Excess Molar Volume;Prigogine-Flory-Patterson Theory;Treszczanowicz-Benson Association Model;Graph Theoretical Approach
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