Adsorption kinetics and thermodynamics of water-insoluble crosslinked β-cyclodextrin polymer for phenol in aqueous solution

Hui Huang; Yifan Fan; Junwei Wang; Haoqi Gao; Shiying Tao

Macromolecular Research, Vol.21, No.7, 726-731, July, 2013

DOI10.1007/s13233-013-1086-6 Export Citation

Adsorption kinetics and thermodynamics of water-insoluble crosslinked β-cyclodextrin polymer for phenol in aqueous solution

Hui Huang^†, Yifan Fan, Junwei Wang, Haoqi Gao, and Shiying Tao¹

School of Chemical Engineering, Ningbo University of Technology, Ningbo, 315016, P. R. China
¹Division of Engineering, University of Nottingham Ningbo China, Ningbo, 315010, P. R. China

E-mail:

A water-insoluble β-cyclodextrin (β-CD) polymer was synthesized by reacting β-CD with hexamethylene diisocyanate, and its adsorption kinetics and thermodynamics for phenol from aqueous solution was investigated. The kinetics of adsorption followed the pseudo-second-order model and the adsorption isotherms could be well fitted by the Freundlich adsorption equation. The values of thermodynamic parameters demonstrated that the adsorption was a physisorption in a spontaneous and exothermic process.

Keywords:β-cyclodextrin;adsorption;phenol;kinetics;thermodynamics

[References]

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Hedges AR, Chem. Rev., 98(5), 2035 (1998)
Del Valle EMM, Process Biochem., 39, 1033 (2004)
Bilensoy E, Cyclodextrins in Pharmaceutics, Cosmetics, and Biomedicine: Current and Future Industrial Applications, John Wiley & Sons, Inc., New Jersey, 2011.
Li N, Wei X, Mei Z, Xiong X, Chen S, Ye M, Ding S, Carbohydr. Res., 346, 1721 (2011)
Xiao JB, Chen XQ, Yu HZ, Xu M, Macromol. Res., 14(4), 443 (2006)
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Sun ZY, Shen MX, Cao GP, Deng J, Liu YA, Liu T, Zhao L, Yuan WK, J. Appl. Polym. Sci., 118(4), 2176 (2010)
Kumar NS, Subbaiah MV, Reddy AS, Krishnaiah A, J. Chem. Technol. Biotechnol., 84(7), 972 (2009)
Dabhade MA, Saidutta MB, Murthy DVR, Afr. J. Biotechnol., 8, 644 (2009)
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Chen QY, Xiao JB, Chen XQ, Jiang XY, Yu HZ, Xu M, Adsorpt. Sci. Technol., 24, 547 (2006)
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Yamasaki H, Makihata Y, Fukunaga K, J. Chem. Technol. Biotechnol., 81(7), 1271 (2006)
Yamasaki H, Matsui H, Fukunaga, K, Jpn. Environ. Conser. Eng., 36, 50 (2007)
Wei QM, Nakato T, Microporous Mesoporous Mater., 26, 84 (2006)
Bhaskar M, Aruna P, Jeevan RJG, Radhakrishnan G, Anal. Chim. Acta, 509, 39 (2004)
Ho YS, Scientometrics, 59, 171 (2004)
Lagergren S, Kungliga Svenska Vetenskapsakademiens. Hanglingar, 24, 1 (1898)
Ho YS, McKay G, Process Saf. Environ. Protect., 76(2), 183 (1998)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Ho YS, McKay G, Process Saf. Environ. Protect., 76(4), 332 (1998)
Ho YS, McKay G, Resour. Conserv. Recycl., 25, 171 (1999)
Wu FC, Tseng RL, Juang RS, Chem. Eng. J., 153(1-3), 1 (2009)
Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31 (1963)
Crini G, Peindy HN, Gimbert F, Robert C, Sep. Sci. Technol., 53, 97 (2007)
Li N, Lei XM, J. Incl. Phenom. Macrocycl. Chem., 74, 167 (2012)
Laidler KJ, J. Chem. Educ., 61, 494 (1984)
Breeuwsma A, J. Colloid Interface Sci., 43, 437 (1973)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
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Ho YS, Porter JF, McKay G, Water Air Soil Pollut., 141, 1 (2002)
Garcia-Delgado RA, Cotouelo-Minguez LM, Rodriguez JJ, Sep. Sci. Technol., 27, 975 (1992)
Kara M, Yuzer H, Sabah E, Celik MS, Water Res., 37, 224 (2003)
Jaycock MJ, Parfitt GD, Chemistry of Interfaces, Ellis Horwood, Chichester, 1981.

[Referenced By]

[1] Engeldinger E, Armspach D, Matt D, Chem. Rev., 103(11), 4147 (2003)

[2] Hedges AR, Chem. Rev., 98(5), 2035 (1998)

[3] Del Valle EMM, Process Biochem., 39, 1033 (2004)

[4] Bilensoy E, Cyclodextrins in Pharmaceutics, Cosmetics, and Biomedicine: Current and Future Industrial Applications, John Wiley & Sons, Inc., New Jersey, 2011.

[5] Li N, Wei X, Mei Z, Xiong X, Chen S, Ye M, Ding S, Carbohydr. Res., 346, 1721 (2011)

[6] Xiao JB, Chen XQ, Yu HZ, Xu M, Macromol. Res., 14(4), 443 (2006)

[7] Sun ZY, Cao GP, Lv H, Zhao L, Liu T, Montastruc L, Iordan N, J. Appl. Polym. Sci., 114(6), 3882 (2009)

[8] Sun ZY, Shen MX, Cao GP, Deng J, Liu YA, Liu T, Zhao L, Yuan WK, J. Appl. Polym. Sci., 118(4), 2176 (2010)

[9] Kumar NS, Subbaiah MV, Reddy AS, Krishnaiah A, J. Chem. Technol. Biotechnol., 84(7), 972 (2009)

[10] Dabhade MA, Saidutta MB, Murthy DVR, Afr. J. Biotechnol., 8, 644 (2009)

[11] Qadeer R, Rehan AH, Turk. J. Chem., 26, 357 (2002)

[12] US-EPA, Toxicological Review of Phenol, 635.R02.006 (2002).

[13] Chen QY, Xiao JB, Chen XQ, Jiang XY, Yu HZ, Xu M, Adsorpt. Sci. Technol., 24, 547 (2006)

[14] Yamasaki H, Makihata Y, Fukunaga K, J. Chem. Technol. Biotechnol., 83(7), 991 (2008)

[15] Yamasaki H, Makihata Y, Fukunaga K, J. Chem. Technol. Biotechnol., 81(7), 1271 (2006)

[16] Yamasaki H, Matsui H, Fukunaga, K, Jpn. Environ. Conser. Eng., 36, 50 (2007)

[17] Wei QM, Nakato T, Microporous Mesoporous Mater., 26, 84 (2006)

[18] Bhaskar M, Aruna P, Jeevan RJG, Radhakrishnan G, Anal. Chim. Acta, 509, 39 (2004)

[19] Ho YS, Scientometrics, 59, 171 (2004)

[20] Lagergren S, Kungliga Svenska Vetenskapsakademiens. Hanglingar, 24, 1 (1898)

[21] Ho YS, McKay G, Process Saf. Environ. Protect., 76(2), 183 (1998)

[22] Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)

[23] Ho YS, McKay G, Process Saf. Environ. Protect., 76(4), 332 (1998)

[24] Ho YS, McKay G, Resour. Conserv. Recycl., 25, 171 (1999)

[25] Wu FC, Tseng RL, Juang RS, Chem. Eng. J., 153(1-3), 1 (2009)

[26] Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31 (1963)

[27] Crini G, Peindy HN, Gimbert F, Robert C, Sep. Sci. Technol., 53, 97 (2007)

[28] Li N, Lei XM, J. Incl. Phenom. Macrocycl. Chem., 74, 167 (2012)

[29] Laidler KJ, J. Chem. Educ., 61, 494 (1984)

[30] Breeuwsma A, J. Colloid Interface Sci., 43, 437 (1973)

[31] Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)

[32] Langmuir I, J. Am. Chem. Soc., 38, 2221 (1916)

[33] Freundlich HMF, Z. Phys. Chem., 57, 385 (1906)

[34] Ho YS, Porter JF, McKay G, Water Air Soil Pollut., 141, 1 (2002)

[35] Garcia-Delgado RA, Cotouelo-Minguez LM, Rodriguez JJ, Sep. Sci. Technol., 27, 975 (1992)

[36] Kara M, Yuzer H, Sabah E, Celik MS, Water Res., 37, 224 (2003)

[37] Jaycock MJ, Parfitt GD, Chemistry of Interfaces, Ellis Horwood, Chichester, 1981.