Simple and rapid synthesis of polyaniline microrods and its electrical properties

D. Ragupathy; Soo Chool Lee; Salem S. Al-Deyab; A. Rajendran

Journal of Industrial and Engineering Chemistry, Vol.19, No.4, 1082-1085, July, 2013

DOI10.1016/j.jiec.2012.12.018 Export Citation

Simple and rapid synthesis of polyaniline microrods and its electrical properties

D. Ragupathy^†, Soo Chool Lee¹, Salem S. Al-Deyab², and A. Rajendran³

Centre for Research & Development, PRIST University, Puducherry 605 007, India
¹Department of Chemical Engineering, Kyungpook National University, Daegu 702 701, South Korea
²Department of Chemistry, Petrochemicals Research Chair, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
³Department of Chemistry, Sir Theagaraya College, Chennai 600 021, Tamil Nadu, India

E-mail:

We report a facile and surfactant assisted synthesis of polyaniline microrods (PANI-MR) by ‘‘single-step chemical oxidative polymerization’’ method. The morphology of the PANI-MR was investigated by fieldemission scanning electron microscopy (FE-SEM). The average diameter of single PANI-MR was calculated to be ~1.3 μm. The physiochemical characterization was examined using UV-visible spectroscopy, Fourier transform infrared spectroscopy and cyclic voltammetry. The electrical conducting property of the PANI-MR was analyzed using four-probe measurement method.

Keywords:Microrod;Aniline;Electrical;Polymerization;Surfactant

[References]

Su K, Nuraje N, Zhang LZ, Chu IW, Peetz RM, Matsui H, Yang NL, Adv. Mater., 19(5), 669 (2007)
Chen HZ, Xu RS, Sun Q, Lam JWY, Wang M, Tang BZ, Polymers for Advanced Technologies., 11, 442 (2000)
Gerard M, Chaubey A, Malhotra BD, Biosensors and Bioelectronics., 17, 345 (2002)
Basavaraja C, Kim NR, Jo EA, Huh DS, Macromol. Res., 18(3), 222 (2010)
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Shirakawa H, Louis EJ, MacDiarmid AG, Chiang CK, Heeger AJ, Journal of the Chemical Society . Chemical Communications., 16, 578 (1977)
Wu CG, Bein T, Science, 264(5166), 1757 (1994)
Huang JX, Virji S, Weiller BH, Kaner RB, J. Am. Chem. Soc., 125(2), 314 (2003)
Virji S, Huang J, Kaner RB, Weiller BH, Nano Letters., 4, 491 (2004)
Liu YD, Fang FF, Choi HJ, Soft Matter., 7, 2782 (2011)
Yang JP, Burkinshaw SM, Zhou J, Monkman AP, Brown PJ, Adv. Mater., 15(13), 1081 (2003)
Jackowska K, Biegunski AT, Tagowska M, Journal of Solid State Electrochemistry., 12, 437 (2008)
Schuth F, Chemistry of Materials., 13, 3184 (2001)
Liang L, Liu J, Exarhos GJ, Lin Y, Angewandte Chemie. International Edition (in English)., 41, 3665 (2002)
Xia MW, MacDiarmid AG, Chemistry of Materials., 7, 443 (1995)
Tan S, Belanger D, J. Phys. Chem. B, 109(49), 23480 (2005)
Tung SP, Hwang BJ, J. Membr. Sci., 241(2), 315 (2004)
Faraji M, Yamini Y, Tahmasebi E, Saleh A, Nourmohammadian F, Journal of Iranian Chemical Society, 7, S130 (2010)
Chen WC, Wen TC, Hu CC, Gopalan A, Electrochim. Acta, 47(8), 1305 (2002)
Wen TC, Chen YH, Gopalan A, Materials Chemistry and Physics., 77, 559 (2002)
Reddy KR, Sin BC, Ryu KS, Kim JC, Chung HE, Lee YG, Synthetic Metals., 159, 595 (2009)
Zhou D, Li Y, Wang J, Xu P, Han X, Materials Letters., 65, 3601 (2011)
Wei ZX, Zhang ZM, Wan MX, Langmuir, 18(3), 917 (2002)
Ragupathy D, Gomathi P, Lee SC, Al-Deyab SS, Lee SH, Ghim HD, J. Ind. Eng. Chem., 18(4), 1213 (2012)
Funrhop JH, Helfrich W, Chemical Reviews., 93, 1565 (1993)
Kim BJ, Oh SG, Han MG, Im SS, Synthetic Metals., 122, 297 (2001)
Harada M, Adachi M, Adv. Mater., 12(11), 839 (2000)

[Referenced By]

[1] Su K, Nuraje N, Zhang LZ, Chu IW, Peetz RM, Matsui H, Yang NL, Adv. Mater., 19(5), 669 (2007)

[2] Chen HZ, Xu RS, Sun Q, Lam JWY, Wang M, Tang BZ, Polymers for Advanced Technologies., 11, 442 (2000)

[3] Gerard M, Chaubey A, Malhotra BD, Biosensors and Bioelectronics., 17, 345 (2002)

[4] Basavaraja C, Kim NR, Jo EA, Huh DS, Macromol. Res., 18(3), 222 (2010)

[5] Patil AO, Wudl F, Heeger AJ, Chemical Reviews., 88, 183 (1988)

[6] Shirakawa H, Louis EJ, MacDiarmid AG, Chiang CK, Heeger AJ, Journal of the Chemical Society . Chemical Communications., 16, 578 (1977)

[7] Wu CG, Bein T, Science, 264(5166), 1757 (1994)

[8] Huang JX, Virji S, Weiller BH, Kaner RB, J. Am. Chem. Soc., 125(2), 314 (2003)

[9] Virji S, Huang J, Kaner RB, Weiller BH, Nano Letters., 4, 491 (2004)

[10] Liu YD, Fang FF, Choi HJ, Soft Matter., 7, 2782 (2011)

[11] Yang JP, Burkinshaw SM, Zhou J, Monkman AP, Brown PJ, Adv. Mater., 15(13), 1081 (2003)

[12] Jackowska K, Biegunski AT, Tagowska M, Journal of Solid State Electrochemistry., 12, 437 (2008)

[13] Schuth F, Chemistry of Materials., 13, 3184 (2001)

[14] Liang L, Liu J, Exarhos GJ, Lin Y, Angewandte Chemie. International Edition (in English)., 41, 3665 (2002)

[15] Xia MW, MacDiarmid AG, Chemistry of Materials., 7, 443 (1995)

[16] Tan S, Belanger D, J. Phys. Chem. B, 109(49), 23480 (2005)

[17] Tung SP, Hwang BJ, J. Membr. Sci., 241(2), 315 (2004)

[18] Faraji M, Yamini Y, Tahmasebi E, Saleh A, Nourmohammadian F, Journal of Iranian Chemical Society, 7, S130 (2010)

[19] Chen WC, Wen TC, Hu CC, Gopalan A, Electrochim. Acta, 47(8), 1305 (2002)

[20] Wen TC, Chen YH, Gopalan A, Materials Chemistry and Physics., 77, 559 (2002)

[21] Reddy KR, Sin BC, Ryu KS, Kim JC, Chung HE, Lee YG, Synthetic Metals., 159, 595 (2009)

[22] Zhou D, Li Y, Wang J, Xu P, Han X, Materials Letters., 65, 3601 (2011)

[23] Wei ZX, Zhang ZM, Wan MX, Langmuir, 18(3), 917 (2002)

[24] Ragupathy D, Gomathi P, Lee SC, Al-Deyab SS, Lee SH, Ghim HD, J. Ind. Eng. Chem., 18(4), 1213 (2012)

[25] Funrhop JH, Helfrich W, Chemical Reviews., 93, 1565 (1993)

[26] Kim BJ, Oh SG, Han MG, Im SS, Synthetic Metals., 122, 297 (2001)

[27] Harada M, Adachi M, Adv. Mater., 12(11), 839 (2000)