Experimental values of density, viscosity, and refractive index at 298.15, 303.15, and 308.15 K, and the speed of sound at 298.15 K, for the binary mixtures of 2-chloroethanol with n-alkanols (C-1-C-6) are presented over the entire mole fraction range. Using these data, excess molar volume and deviations in viscosity, Delta eta speed of sound, Delta u, and isentropic compressibility, Delta k(S), have been calculated. Excess quantities and deviations have been fitted to the Redlich-Kister equation to derive the binary coefficients with the standard errors between the experimental and calculated quantities. Sign and magnitude of the mixing quantities have been discussed to study the nature of molecular interactions in binary mixtures.