Experimental values of density, viscosity, and refractive index at (298.15, 303.15, and 308.15) K and the speed of sound at 298.15 K for the binary mixtures of acrylonitrile with methyl, acetate, ethyl acetate, propyl acetate, butyl acetate, and 3-methylbutyl-2-acetate are presented over the whole range of mixture composition. From these data, excess molar volume, deviations in viscosity, speed of sound, isentropic compressibility, and Lorenz-Lorentz molar refractivity have been calculated. These results are fitted to Redlich-Kister type polynomial equation of the third degree to derive the binary coefficients. The standard error values are estimated between the calculated and experimental data.