Heterogeneous photocatalytic degradation of 4-chlorophenol by immobilization of cobalt tetrasulphophthalocyanine onto MCM-41

Azadeh Ebrahimian Pirbazari; Mohammad Ali Zanjanchi

Korean Journal of Chemical Engineering, Vol.31, No.2, 218-223, February, 2014

DOI10.1007/s11814-013-0223-4 Export Citation

Heterogeneous photocatalytic degradation of 4-chlorophenol by immobilization of cobalt tetrasulphophthalocyanine onto MCM-41

Azadeh Ebrahimian Pirbazari^{1, 2, †}, and Mohammad Ali Zanjanchi²

¹Faculty of Fouman, College of Engineering, University of Tehran, P. O. Box 43515-1155, Fouman 43516-66456, Iran
²Department of Chemistry, Faculty of Science, University of Guilan, P. O. Box 1914, Rasht 41335, Iran

E-mail:

The photocatalytic activity of cobalt tetrasulphophthalocyanine immobilized onto MCM-41 was investigated for photocatalytic degradation of 4-chlorophenol (4-CP) in aqueous solutions. Immobilization of cobalt tetrasulphophthalocyanine complex to the walls of MCM-41 was performed by pre-anchorage of 3-(aminopropyl)-triethoxysilane (APTES) onto MCM-41 via post-synthesis method. X-ray diffraction, nitrogen physisorption, diffuse reflectance spectroscopy, energy-dispersive X-ray and FT-IR methods were used to characterize the product. Photocatalytic efficiency of the prepared photocatalyst for degradation of 4-CP was tested under illumination of UV-A and visible light. The reaction intermediates were identified by gas chromatography-mass spectrometry (GC-MS) technique.

Keywords:Phthalocyanine;MCM-41;Immobilization;4-Chlorophenol;Photocatalytic Degradation

[References]

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[1] Orloff K, Falk H, Int. J. Hyg. Environ. Health, 206, 291 (2003)

[2] Pera-Titus M, Garcia-Molina V, Banos MA, Gimenez J, Esplugas S, Appl. Catal. B: Environ., 47(4), 219 (2004)

[3] Abramovic BF, Anderluh VB, Topalov AS, Gaal FF, APTEFF, 35, 1 (2004)

[4] Pelizzetti E, Maurino V, Minero C, Carlin V, Pramauro E, Zerbinati O , Tosato ML, Environ. Sci. Technol., 24, 1559 (1990)

[5] Ghaly MY, Hartel G, Mayer R, Haseneder R, Waste Manage., 21, 41 (2001)

[6] Gaya UI, Abdullah AH, Zainal Z, Hussein MZ, J. Hazard. Mater., 168(1), 57 (2009)

[7] Serpone N, Pelizzetti EE, Photocatalysis, Fundamentals and Applications (1989)

[8] Fox MA, Dulay MT, Chem. Rev., 93, 341 (1993)

[9] Ollis DF, Al-Ekabi H, Photocatalytic Purification and Treatment of Water and Air, Elsevier, Amsterdam (1993)

[10] Bahnemann D, Cunningham J, Fox MA, Pelizzetti E, Pichat P, Serpone N, Aqua. Surf. Photochem., 261 (1994)

[11] Sakthivel S, Kisch H, Chem. Phys. Chem., 4, 487 (2003)

[12] Kisch H, Macyk W, Nachricht. Chem., 50, 1078 (2002)

[13] Kisch H, Weiss H, Adv. Funct. Mater., 12(8), 483 (2002)

[14] Kisch H, Macyk W, Chem. Phys. Chem., 3, 399 (2002)

[15] Alvaro M, Carbonell E, Espla M, Garcia H, Appl. Catal. B: Environ., 57(1), 37 (2005)

[16] Ozoemena K, Kuznetsova N, Nyokong T, J. Mol. Catal. A-Chem., 176(1-2), 29 (2001)

[17] Sun L, Von Gersdorff J, Sobek J, Kurreck H, Tetrahedron, 51, 3535 (1995)

[18] Harriman A, Energy Resour. Photochem. Catal., 163 (1983)

[19] Czaplicka M, Science of the Total Environ., 322, 21 (2004)

[20] Weber JH, Bush DH, Inorg. Chem., 4, 469 (1965)

[21] Zanjanchi MA, Asgari S, Solid State Ion., 171(3-4), 277 (2004)

[22] Moller K, Bein T, Chem. Mater., 10, 2950 (1998)

[23] Pirouzmand M, Amini MM, Safari N, J. Colloid Interface Sci., 319(1), 199 (2008)

[24] Ernst S, Selle M, Micropor. Mesopore. Mater, 27, 355 (1999)

[25] Law KY, Chem. Rev., 93, 449 (1993)

[26] Ozoemena K, Kuznetsova N, Nyokong T, J. Photochem. Photobiol. A, 39, 217 (2001)

[27] Liu CJ, Li SG, Pang WQ, Che CM, Chem. Commun., 65 (1997)

[28] Gao R, Stark J, Bahnemann DW, Rabani J, J. Photochem. Photobiol. A: Chem., 148, 387 (2002)

[29] Machado AEH, Franca MD, Velani V, Magnino GA, Velani HMM, Freitas FS, Muller Jr.PS, Sattler C, Schmucker M, Int. J. Photoenergy, 1 (2008)

[30] Nash T, Biochem. J., 55, 416 (1953)

[31] Chaliha S, Bhattacharyya KG, Catal. Today, 141, 225 (2009)

[32] Chaliha S, Bhattacharyya KG, Paul P, Clean, 36, 448 (2008)

[33] Bian WJ, Song XH, Liu DQ, Zhang J, Chen XH, J. Hazard. Mater., 192(3), 1330 (2011)

[34] Wu L, Li AM, Gao GD, Fei ZH, Xu SR, Zhang QX, J. Mol. Catal. A-Chem., 269(1-2), 183 (2007)

[35] Rao NN, Dubey AK, Mohanty S, Khare P, Jain R, Kau SN, J. Hazard. Mater., 101(3), 301 (2003)

[36] Konstantinou IK, Sakkas VA, Albanis TA, Appl. Catal. B: Environ., 34(3), 227 (2001)

[37] Serpone N, Lawless D, Terzian R, Meisel D, in: R. A. Mackay, J. Texter (Eds.), Electrochemistry in Colloids and Dispersions, VCH, New York, NY, 399 (1992)